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Georgiy Borisovich Shul’pin ((ロシア語:Георгий Борисович Шульпи́н), also Shulpin) was born in 1946 in Moscow, Russia. He graduated with a M.S. degree in chemistry from the Chemistry Department of Moscow State University in 1969. Between 1969 and 1972, he was a postgraduate student at the Nesmeyanov Institute of Organoelement Compounds (Academy of Sciences of the USSR, Moscow) under the direction of Prof. A. N. Nesmeyanov and received his Ph.D. in organometallic chemistry in 1975. He received his Dr. of Sciences degree in 2013. ==Career== Since 1978, Shul’pin has been working at the N. N. Semenov Institute of Chemical Physics at the Russian Academy of Sciences in Moscow. He is currently a senior scientific researcher. His research activities concern metal complex catalysis,〔B. Plietker (Ed.), “Iron Catalysis in Organic Chemistry: Reactions and Applications”, WILEY-VCH, Weinheim, 2008, pp. 77, 80. ISBN 978-3-527-31927-5〕 oxidation of hydrocarbons,〔W. Carruthers, I. Coldham, “Modern methods of organic synthesis”, Fourth edition, Cambridge University Press, 2004, p. 371. ISBN 0-521-77097-1 http://books.google.com/books?id=7gPnWf4UDLsC&printsec=frontcover&dq=W.+Carruthers,+I.+Coldham,+%E2%80%9CModern+methods+of+organic+synthesis%E2%80%9D,&source=bl&ots=tz9VK72O1x&sig=zZiihLSWEboZeiyALlziAqkfwDI&hl=ru&ei=jVoYTZufMISSOpbEsIIJ&sa=X&oi=book_result&ct=result&resnum=1&sqi=2&ved=0CBcQ6AEwAA#v=onepage&q&f=false〕〔R. H. Crabtree (Ed.), “Energy Production and Storage: Inorganic Chemical Strategies for a Warming World”, J. Wiley & Sons, Inc., Chichester, West Sussex, 2010. Chapter (pp. 101-142): B. G. Hashiguchi, C. H. Hövelmann, S. M. Bischof, K. S. Lokare, C. H. Leung, R. A. Periana, “Methane-to-Methanol Conversion”, pp. 11-113, 131, 134, 137. ISBN 978-0-470-74986-9〕 particularly using “green oxidants” H2O2〔W. R. Sanderson, “Hydrogen Peroxide in Waste Minimisation – Current and Potential Contributions”, in: J. H. Clark, D. J. Macquarrie (Eds.), “Handbook of Green Chemistry and Technology”, Blackwell, Oxford, 2002, Chapter11, pp. 258-305. ISBN 0-632-05715-7〕 and O2,〔F. Cavani, S. Alini, “Syntheis of Adipic Acid: On the Way to More Sustainable Production”, Chapter 7 in: F. Cavani, G. Centi, S. Perathoner, F. Trifiró (Eds.), “Sustainable Industrial Chemistry”, WILEY-VCH, Weinheim, 2009. ISBN 978-3-527-31552-9〕 activation〔T. B. Gunnoe, “Metal-Mediated Carbon-Hydrogen Bond Activation”, Chapter 11 in: A. Bacac (Ed.), “Physical Inorganic chemistry: Reactions, Processes, and Applications”, J. Wiley & Sons, Inc., New Jersey, 2010, pp. 495-550. ISBN 978-0-470-22420-5〕 and functionalization〔P. W. N. M. van Leeuwen, “Homogeneous Catalysis: Understanding the Art”, Kluwer, Dordrecht, 2004, Chapter 19 (“C-H Functionalization”). ISBN 1-4020-1999-8〕〔R. B. King, “Encyclopedia of Inorganic Chemistry: S”, Second Edition, J. Wiley & Sons, Inc., 2005, p. 4381. ISBN 978-0-470-86078-6〕〔C.-J. Li, T.-H. Chan, “Comprehensive Organic Reactions in Aqueous Media”, J. Wiley & Sons, Inc., New Jersey, 2007, ISBN 978-0-471-76129-7〕〔J.-Q. Yu, Z. Shi (Eds.), “C-H Activation”, Springer, Heidelberg, 2010. 〕 of C–H bonds in saturated and aromatic hydrocarbons, organometallic chemistry. Other interests include photocatalysis,〔T. Bitterwolf, “Photochemistry of Transition Metal Complexes”, in: “Encyclopedia of Inorganic Chemistry”, Wiley Online Library, 2006, Online ISBN 978-0-470-86210-0 〕 biomimetic oxidations〔S. Tanase, E. Boluwman, “Selective Conversion of Hydrocarbons with H2O2 Using Biomimetic Non-heme Iron and Manganese Oxidation Catalysts”, in: R. Van Eldik, J. Reedijk (Eds.), “Adv. Inorg. Chem.: Homogeneous Biomimetic Oxidation Catalysis”, vol. 58, Academic Press, London, 2006, pp. 55, 63, 70. ISBN 978-0-12-023658-9〕 and ecological chemistry. In eighties Shul’pin together with A.E. Shilov discovered the metalation reaction of arenes by hexachloroplatinate which is stimulated by heating, light or gamma-irradiation〔R. H. Crabtree, “The organometallic chemistry of alkanes”, Chem. Rev. 1985, 85, 245-269. 〕〔V. K. Jain, G. S. Rao, L. Jain, “The Organic Chemistry of Platinum(IV)”, in: “Advances in Organometallic Chemistry”, vol. 27, Academic Press, Inc., 1987, p. 116. ISBN 0-12-031127-5〕〔G. K. Anderson, “Platinum-Carbon sigma-Bonded Complexes”, in: R. J. Puddephatt (Ed.), “Comprehensive Organometallic Chemistry II”, Elsevier, 1995, p. 518. ISBN 0-08-042316-7〕〔L. Johansson, O. B. Ryan, C. Rømming, M. Tilset, “Unexpected Selectivities in C-H Activations of Toluene and p-Xylene at Cationic Platinum(II) Diimine Complexes.”, J. Am. Chem. Soc. 2001, 123, 6579-6590. 〕〔J. Mamtora, S. H. Crosby, C. P. Newman, G. J. Clarkson, J. P. Rourke, “Platinum(IV) Complexes: C-H Activation at Low Temperatures”, Organometallics 2008, 27, 5559–5565. 〕〔A. M. Voutchkova, R. H. Crabtree, J. Mol. Catal., A: Chem. 2009, 312, 1-6. 〕〔P. Sehnal, R. J. K. Taylor, I. J. S. Fairlamb, “Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis”, Chem. Rev. 2010, 110, 824–889. 〕 and affords stable sigma-aryl Pt(IV) complexes (“Shul’pin’s reaction”).〔M. Ochiai, K. Fukui, S. Iwatsuki, K. Ishihara, K. Matsumoto, “Synthesis of aryl-platinum dinuclear complexes via ortho C-H bond activation of phenol and transmetalation of arylboronic acid”, Organometallics, 2005, 24, 5528-5536. 〕 He developed aerobic oxygenation of saturated hydrocarbons under visible light irradiation catalyzed by oxo and chloride complexes of transition metals〔J.-E. Bäckvall (Ed.), “Modern Oxidation Methods”, WILEY-VCH Verlag, Weinheim, 2004, p. 121. ISBN 3-527-30642-0 http://www.wiley-vch.de/publish/en/books/bySubjectCH00/ISBN3-527-30642-0/?sID=8245b6d09961810d71a72151875fb5a1〕 and discovered three efficient systems for the catalytic oxidations with hydrogen peroxide. Catalytic combinations: i) “vanadium derivative plus pyrazine-2-carboxylic acid (PCA)”;〔P. P. Knops-Gerrits, C. A. Trujillo, B. Z. Zhan, X. Y. Li, P. Rouxhet, P. A. Jacobs, “Oxidation catalysis with well-characterised vanadyl bis-bipyridine complexes encapsulated in NaY zeolite”, Topics in Catalysis, 1996, 437-449. 〕〔W. A. Herrmann (Ed.), “Synthetic Methods of Organometallic and Inorganic Chemistry: Catalysis (Herrmann/Brauer, vol. 10: Catalysis)”, Georg Thieme Verlag, Stuttgart, 2002, Chapter 10, pp. 117-121. ISBN 3-13-115161-7〕〔G. A. Olah, A. Molnár, “Hydrocarbon Chemistry”, Second edition, J. Wiley & Sons, Inc., New Jersey, 2003, pp. 520 and 565. ISBN 0-471-41782-3 http://www.wiley-vch.de/publish/en/books/bySubjectCH00/ISBN0-471-41782-3/?sID=8245b6d09961810d71a72151875fb5a1〕〔J.-E. Bäckvall (Ed.), “Modern Oxidation Methods”, WILEY-VCH Verlag, Weinheim, 2004, p. 121. ISBN 3-527-30642-0〕〔R. Z. Khaliullin, A. T. Bell, M. Head-Gordon, “A Density Functional Theory Study of the Mechanism of Free Radical Generation in the System Vanadate/PCA/H2O2”, J. Phys. Chem. B 2005, 109, 17984-17992. 〕〔Z. Rappoport (Ed.), “The Chemistry of Peroxides”, J. Wiley & Sons, Inc., 2006, p. 1116. ISBN 978-0-470-86274-2〕 ii) “a dinuclear manganese(IV) complex plus carboxylic acid”;〔K. F. Sibbons, K. Shastri, M. Watkinson, “The application of manganese complexes of ligands derived from 1,4,7-triazacyclononane in oxidative catalysis (a review)”, Dalton Trans. 2006, 645-661. 〕〔“Alkanes: Webster’s Facts and Phrases”, ICON, San Diego, 2008, p. 41. ISBN 0-546-67675-8〕 iii) “an osmium complex plus amine”.〔G. A. Olah, A. Molnár, “Hydrocarbon Chemistry”, Second edition, J. Wiley & Sons, Inc., New Jersey, 2003, pp. 521 and 566. ISBN 0-471-41782-3. http://www.wiley-vch.de/publish/en/books/bySubjectCH00/ISBN0-471-41782-3/?sID=8245b6d09961810d71a72151875fb5a1〕 G. B. Shul’pin proposed a simple and convenient method for the estimation of concentration of alkyl hydroperoxides formed in alkane oxidations by molecular oxygen or peroxides. This method (gas-chromatographic analysis of the samples before and after their reduction by triphenylphosphine, “Shul’pin’s method”) is widely used in chemical practice.〔Q. Yuan, W. Deng, Q. Zhang, Y. Wang, “Osmium-catalyzed selective oxidations of methane and ethane with hydrogen peroxide in aqueous medium”, Adv. Synth. Catal. 2007, 349, 1199–1209. 〕〔L. Zhou, Y. Chen, X. Yang, Y. Su, W. Zhang, J. Xu, “Electronic effect of substituent of quinones on their catalytic performance in hydrocarbons oxidation”, Catal. Let. 2008, 125, 154-159. 〕〔G. S. Mishra, T. F. S. Silva, L. M. D. R. S. Martins, A. J. L. Pombeiro,”Scorpionate complexes of vanadium(III or IV) as catalyst precursors for solvent-free cyclohexane oxidation with dioxygen”, Pure Appl. Chem., 2009, 81, 1217–1227. 〕〔K. T. Mahmudov, M. N. Kopylovich, M. F. C. G. da Silva, P. J. Figiel, Y. Y. Karabach, A. J. L. Pombeiro, “New copper(II) dimer and its catalytic activity in cyclohexane and benzyl alcohol oxidations”, J. Mol. Catal., A: Chem. 2010, 318, 44-50. 〕〔P. Roy, M. Manassero, “Tetranuclear copper(II)–Schiff-base complexes as active catalysts for oxidation of cyclohexane and toluene”, Dalton Trans. 2010, 1539-1545. 〕〔S. Bose, A. Pariyar, A. N. Biswas, P. Das, P. Bandyopadhyay, “Mild oxidation of hydrocarbons by tert-butyl hydroperoxide catalyzed by electron deficient manganese(III) corroles”, J. Mol. Catal., A: Chem. 2010, 332, 1-6 .〕 G. B. Shul’pin has published about 250 papers in chemical journals. He is the author (coauthor) of monographs〔S. P. Gubin, G. B. Shul’pin, “The Chemistry of Complexes with Metal-Carbon Bonds”, Novosibirsk, Nauka, 1984, 280 pp. (in Russian).〕〔G. B. Shul’pin, “Organic Reactions Catalyzed by Metal Complexes”, Nauka, Moscow, 1988 (285 pp., in Russian). ISBN 5-02-001351-X〕〔A. E. Shilov, G. B. Shul’pin, “Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes”, Kluwer Academic Publishers, Dordrecht/Boston/London, 2000, (548 pp.) (Springer, ISBN 978-0-7923-6101-5) http://www.springer.com/chemistry/physical+chemistry/book/978-0-7923-6101-5〕〔G. B. Shul’pin, “Oxidations of C–H Compounds Catalyzed by Metal Complexes”, in: "Transition Metals for Organic Synthesis", Eds. M. Beller, C. Bolm, Second Edition, WILEY-VCH Verlag, Weinheim, 2004, Vol. 2, Chapter 2.2, pp. 215–241. ISBN 3-527-30613-7, ISBN 978-3-527-30613-8〕 and reviews.〔A. E. Shilov, G. B. Shul’pin, “Activation of C–H Bonds by Metal Complexes”, Chem. Rev. 1997, 97(8), 2879–2932. 〕〔G. B. Shul’pin, "Metal-catalysed hydrocarbon oxygenations in solutions: the dramatic role of additives: a review", J. Mol. Catal. A: Chem. 2002, 189, 39–66. 〕〔G. B. Shul’pin, "Metal-catalysed hydrocarbon oxidations", Comptes Rendus, Chimie 2003, 6, 163–178. 〕〔G. B. Shul’pin, “Hydrocarbon Oxygenations with Peroxides Catalyzed by Metal Compounds”, Mini-Rev. Org. Chem. 2009, 6, 95–104.〕〔G. B. Shul’pin, “Selectivity enhancement in functionalization of C–H bonds: A review”, Org. Biomol. Chem. 2010, 8, 4217–4228. 〕 He has also written numerous books on popular science (for example,〔G. B. Shul'pin, The World of Unusual Molecules: Organometallic Complexes, Moscow, Nauka, 1986, 176 pp. (in Russian).〕〔G. B. Shul'pin, Learning About Chemistry, Moscow, Mir Publishers, 1989, 232 pp. (in English). ISBN 5-03-000542-0〕〔C. Shulpin, Que es la quimica organica, Ediciones Quinto Sol, Mexico, 1988, 272 pp. (in Spanish). ISBN 968-6136-46-0〕〔G. B. Shulpin, Quimica para todos, Moscu, Editorial Mir, 1990, 264 pp. (in Spanish). ISBN 5-03-001313-X〕) and articles in popular scientific journals. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Georgiy B. Shul'pin」の詳細全文を読む スポンサード リンク
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